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Abstract Submarine groundwater discharge is increasingly recognized as an important component of the oceanic geochemical budget, but knowledge of the distribution of this phenomenon is limited. To date, reports of meteoric inputs to marine sediments are typically limited to shallow shelf and coastal environments, whereas contributions of freshwater along deeper sections of tectonically active margins have generally been attributed to silicate diagenesis, mineral dehydration, or methane hydrate dissociation. Here, using geochemical fingerprinting of pore water data from Site J1003 recovered from the Chilean Margin during D/V JOIDES Resolution Expedition 379 T, we show that substantial offshore freshening reflects deep and focused contributions of meteorically modified geothermal groundwater, which is likely sourced from a reservoir ~2.8 km deep in the Aysén region of Patagonia and infiltrated marine sediments during or shortly after the last glacial period. Emplacement of fossil groundwaters reflects an apparently ubiquitous phenomenon in margin sediments globally, but our results now identify an unappreciated locus of deep submarine groundwater discharge along active margins with potential implications for coastal biogeochemical processes and tectonic instability.more » « less
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Abstract Sediment cores recently collected from the Chilean Margin during D/VJOIDES ResolutionExpedition 379T (JR100) document variability in shipboard‐generated records of the green/blue (G/B) ratio. These changes show a strong coherence with benthic foraminiferal δ18O, Antarctic ice core records, and sediment lithology (e.g., higher diatom abundances in greener sediment intervals), suggesting a climate‐related control on the G/B. Here, we test the utility of G/B as a proxy for diatom productivity at Sites J1002 and J1007 by calibrating G/B to measured biogenic opal. Strong exponential correlations between measured opal% and the G/B were found at both sites. We use the empirical regressions to generate high‐resolution records of opal contents (opal%) on the Chilean Margin. Higher productivity tends to result in more reducing sedimentary conditions. Redox‐sensitive sedimentary U/Th generally co‐varies with the reconstructed opal% at both sites, supporting the association between sediment color, sedimentary U/Th, and productivity. Lastly, we calculated opal mass accumulation rate (MAR) at Site J1007 over the last ∼150,000 years. The G/B‐derived opal MAR record from Site J1007 largely tracks existing records derived from traditional wet‐alkaline digestion from the south and eastern equatorial Pacific (EEP) Ocean, with a common opal flux peak at ∼50 ka suggesting that increased diatom productivity in the EEP was likely driven by enhanced nutrient supply from the Southern Ocean rather than dust inputs as previously suggested. Collectively, our results identify the G/B ratio as a useful tool with the potential to generate reliable, high‐resolution paleoceanographic records that circumvent the traditionally laborious methodology.more » « less
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The Line Islands Ridge (LIR), located south of the Hawaiian Islands between 7°N and 1°S, is one of the few large central Pacific regions shallower than the regional carbonate compensation depth. Thick sequences of carbonate sediments have accumulated around the LIR despite it being located in the sediment-starved central tropical Pacific. The LIR is an important source of carbonates to the surrounding region and deposition around the LIR has expanded the equatorial Pacific carbonate sediment tongue by about 5% of its total area. Furthermore, sediments on the ridge are potentially important paleoceanographic archives. A recent survey at the crest of the LIR finds evidence for high current activity, significant erosion, but overall net sediment deposition. Currents are strong enough to form sediment waves and lee drifts in the Palmyra Basin, at the northern terminus of the LIR. Sediments along the LIR are pelagic foraminiferal sands that are easily eroded and flow out into the surrounding abyssal plain in active submarine channel systems. As channels migrate, pelagic sediments fill in the abandoned channel arms. Despite significant sediment losses from the top of the ridge, 1.3 km of sediment has accumulated in the upper Palmyra Basin over basement formed 68 to 85 million years ago (Ma). Late Neogene erosion may be more extensive than earlier erosion cycles, in response to reduced sediment production as the Palmyra Basin exited the high productivity equatorial latitudes. Sediments with good stratigraphic order needed for paleoceanographic study are limited in this dynamic sedimentary environment, but can be found with proper survey.more » « less
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Abstract Much uncertainty exists about the state of the oceanic and atmospheric circulation in the tropical Pacific over the last glacial cycle. Studies have been hampered by the fact that sediment cores suitable for study were concentrated in the western and eastern parts of the tropical Pacific, with little information from the central tropical Pacific. Here we present information from a suite of sediment cores collected from the Line Islands Ridge in the central tropical Pacific, which show sedimentation rates and stratigraphies suitable for paleoceanographic investigations. Based on the radiocarbon and oxygen isotope measurements on the planktonic foraminiferaGlobigerinoides ruber, we construct preliminary age models for selected cores and show that the gradient in the oxygen isotope ratio ofG. ruberbetween the equator and 8°N is enhanced during glacial stages relative to interglacial stages. This stronger gradient could reflect enhanced equatorial cooling (perhaps reflecting a stronger Walker circulation) or an enhanced salinity gradient (perhaps reflecting increased rainfall in the central tropical Pacific).more » « less
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